SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS

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SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS

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- SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS
- Journal of University of Jinan(Social Science Edition) Issue 1, Pages: 58-63(1996)
- 作者机构：
  
  1.   济南大学
  2.   中国科学院兰州化学物理研究所
  3.   Laboratoire de chimie de coordination
  4.   UA CNRS  ,416
  5.   Universite Louis pasteur
  6.   4 rue Blaise Pascal
  7.   F— strasbourg Cedex  ,67070
  8.   France
- 作者简介：
- 基金信息：
- DOI：
  CLC： O641
- Published：1996，
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[1]焦凤英,徐吉春,张新堂,殷元骐,Pierre Braunstein,JackyRose.原子簇的合成方法、性质表征与结构[J].济南大学学报(综合版),1996,{4}(01):58-63.

SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS. [J]. Journal of University of Jinan(Social Science Edition) (1):58-63(1996)
[1]焦凤英,徐吉春,张新堂,殷元骐,Pierre Braunstein,JackyRose.原子簇的合成方法、性质表征与结构[J].济南大学学报(综合版),1996,{4}(01):58-63. DOI：

SYNTHESIS METHOD, CHARACTERIZATION OF ATOMIC CLUSTERS AND THE STRUCTURE ANALYSIS. [J]. Journal of University of Jinan(Social Science Edition) (1):58-63(1996) DOI：

摘要

利用给电子有机和无机配位体的交换反应和金属卤化物与羰基金属阴离子的复分解反应

合成异核原子簇具有反应条件温和易于控制

收率较高的特点。本文描述Fe

（CO）

（C

）

等11个原子簇的合成方法

配位状态与簇核的结构。

Abstract

Exchang reaction of carbonyl with organic or inorganic ligands of electron-doner and metathesis of metal halids with carbonyl metal negative ion have been used to prepare some heteronuclear atomic clusters. The reaction condition are often moderate. They performed easier and have

a mord yield. In This paper

Synthesis

coordination slate

and framwork of cluster nuclear of Fe3（CO）9（C2H2）3 ect

which have 11 cluster

were described.

关键词

异核原子簇过渡金属羰基化合物配合物

Keywords

heteronuclear dustertransition metal carbonyl compoundcoordination complex

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